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Pastimes : Plastics to Oil - Pyrolysis and Secret Catalysts and Alterna

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To: PaperProphet who wrote (22008)4/7/2012 11:38:29 PM
From: Steady_onRead Replies (4) of 53574
 
I have answered your question. Please don't waste the time of this board by bringing it up over and over.

The company has stated several times that the #2 processor is in operation. The proof of that will be in the 1st quarter filing or it will show that it was not in operation.

This board will not accept any emails, relayed phone calls, or other communications as evidence of anything. So what's your point in asking?

I have stated my opinion. I made it clear that it was an opinion. Let's just wait for the hard information to become evident.

I am aware that pyrolysis without a catalyst makes much smaller hydrocarbon chains. I am also aware that refineries routinely crack longer chains of crude oil into shorter chains. What's your point?

I assume that you are aware of the equipment and processes that refineries use to crack those longer hydrocarbon chains. Are you suggesting that JBI uses these technologies?

For example: from en.wikipedia.org

Fluid Catalytic cracking
Main article: Fluid catalytic cracking
Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the U.S., due to the high demand for gasoline. [2] [3] [4] The process was first used in around 1942 and employs a powdered catalyst. During the Second World War, in contrast to the Axis Forces which suffered severe shortages of gasoline and artificial rubber, the Allied Forces were supplied with plentiful supplies of the materials. Initial process implementations were based on low activity alumina catalyst and a reactor where the catalyst particles were suspended in a rising flow of feed hydrocarbons in a fluidized bed.

Alumina-catalyzed cracking systems are still in use in high school and university laboratories in experiments concerning alkanes and alkenes. The catalyst is usually obtained by crushing pumice stones, which contain mainly aluminium oxide and silica into small, porous pieces. In the laboratory, aluminium oxide (or porous pot) must be heated.

In newer designs, cracking takes place using a very active zeolite-based catalyst in a short-contact time vertical or upward-sloped pipe called the "riser". Pre-heated feed is sprayed into the base of the riser via feed nozzles where it contacts extremely hot fluidized catalyst at 1230 °F to 1400 °F (665 °C to 760 °C). The hot catalyst vaporizes the feed and catalyzes the cracking reactions that break down the high-molecular weight oil into lighter components including LPG, gasoline, and diesel. The catalyst-hydrocarbon mixture flows upward through the riser for just a few seconds, and then the mixture is separated via cyclones. The catalyst-free hydrocarbons are routed to a main fractionator for separation into fuel gas, LPG, gasoline, naphtha, light cycle oils used in diesel and jet fuel, and heavy fuel oil.

During the trip up the riser, the cracking catalyst is "spent" by reactions which deposit coke on the catalyst and greatly reduce activity and selectivity. The "spent" catalyst is disengaged from the cracked hydrocarbon vapors and sent to a stripper where it is contacted with steam to remove hydrocarbons remaining in the catalyst pores. The "spent" catalyst then flows into a fluidized-bed regenerator where air (or in some cases air plus oxygen) is used to burn off the coke to restore catalyst activity and also provide the necessary heat for the next reaction cycle, cracking being an endothermic reaction. The "regenerated" catalyst then flows to the base of the riser, repeating the cycle.

The gasoline produced in the FCC unit has an elevated octane rating but is less chemically stable compared to other gasoline components due to its olefinic profile. Olefins in gasoline are responsible for the formation of polymeric deposits in storage tanks, fuel ducts and injectors. The FCC LPG is an important source of C3-C4 olefins and isobutane that are essential feeds for the alkylation process and the production of polymers such as polypropylene.

Steam cracking Steam cracking is a petrochemical process in which saturated hydrocarbons are broken down into smaller, often unsaturated, hydrocarbons. It is the principal industrial method for producing the lighter alkenes (or commonly olefins), including ethene (or ethylene) and propene (or propylene).

In steam cracking, a gaseous or liquid hydrocarbon feed like naphtha, LPG or ethane is diluted with steam and briefly heated in a furnace without the presence of oxygen. Typically, the reaction temperature is very high, at around 850°C, but the reaction is only allowed to take place very briefly. In modern cracking furnaces, the residence time is reduced to milliseconds to improve yield, resulting in gas velocities faster than the speed of sound. After the cracking temperature has been reached, the gas is quickly quenched to stop the reaction in a transfer line heat exchanger or inside a quenching header using quench oil.

The products produced in the reaction depend on the composition of the feed, the hydrocarbon to steam ratio and on the cracking temperature and furnace residence time.

Light hydrocarbon feeds such as ethane, LPGs or light naphtha give product streams rich in the lighter alkenes, including ethylene, propylene, and butadiene. Heavier hydrocarbon (full range and heavy naphthas as well as other refinery products) feeds give some of these, but also give products rich in aromatic hydrocarbons and hydrocarbons suitable for inclusion in gasoline or fuel oil. The higher cracking temperature (also referred to as severity) favours the production of ethene and benzene, whereas lower severity produces higher amounts of propene, C4-hydrocarbons and liquid products. The process also results in the slow deposition of coke, a form of carbon, on the reactor walls. This degrades the efficiency of the reactor, so reaction conditions are designed to minimize this. Nonetheless, a steam cracking furnace can usually only run for a few months at a time between de-cokings. Decokes require the furnace to be isolated from the process and then a flow of steam or a steam/air mixture is passed through the furnace coils. This converts the hard solid carbon layer to carbon monoxide and carbon dioxide. Once this reaction is complete, the furnace can be returned to service.
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