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Politics : Formerly About Advanced Micro Devices

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To: Brumar89 who wrote (1003072)3/1/2017 5:53:51 PM
From: PKRBKR  Read Replies (2) of 1572643
 
NF3 gained popularity as a substitute for even more harmful global warming gases that were used in the same types of manufacturing

I actually know a lot about this as I worked on a Sematech committee battling the Clinton/Gore EPA to reduce per-fluorinated hydrocarbons (CF4, C2F6, CHF3, etc.) as they had "High" global warming potentials. These gases are used as silicon, silicon dioxide, Ti and W etch gases and were/are critically important to making semiconductors. Ironically NF3 was offered up as a replacement source of fluorine even with a much higher global warming potential. The NF3 could be cracked in a microwave plasma downstream from the process tool and the F could be water scrubbed away. The other gases were less amenable to plasma destruction so the industry offered this expensive approach and the EPA backed down a bit. Regardless the minuscule emissions of all of these gases don't add up to squat in the atmosphere.

No wonder there is no more silicon being made in Silicon Valley.
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