To: Thor Carlsen who wrote (11996 ) 10/24/1999 10:37:00 PM From: Chuca Marsh Read Replies (1) | Respond to of 14226
Just venting:acusd.edu You are my assistant aboard the Ocean Drilling Program research vessel, JOIDES Resolution. Your job is to measure pH, Fe+2 and H2S concentrations in hydrothermal vent fluids. Your measured data are: [Fe+2] = 0.05 mM/l [H2S ] = 26.9 mM/l pH = 5.6 Fe+2 and H2S data are reproducible and reasonable, but your pH meter has not been working well and your pH data is suspect. You need an alternate way to verify pH data. Your handy biogeochem text tells you that pyrrhotite (FeS) forms according to the following equation: Fe+2 + H2S = FeS + 2H+ Log Ksp = -2.28 M/l Brassy yellow sulfides are abundant in the hydrothermal vent wall rocks, and the X-ray diffraction technician tells you that the mineral is pyrrhotite (not pyrite) . It may be safe to assume that [Fe+2] is pyrrotite solubility controlled. Calculate the expected pH of the fluid from the concentration data you have at hand. Is your measured pH reasonable? step 1. Put all concentrations into uits of M/l [Fe+2] = (0.05mM/l)(1mM/1000mM)(1M/1000mM) = 5 X 10-8 M/l [H2S ] = (26.9mM/l)(1M/1000mM) = 2.69 X 10-2 M/l step 2. Set up the Ksp calculation with [H+] as the unknown, since [H+] with give you pH. Remember that for solids, in this case FeS, the concentration is 1, and that coefficients, such as 2H+ in this case, become exponents of the concentrations, [H+]2. Ksp = [products] [reactants] 10 -2.28M/l = [FeS][H+]2 [FeS] = 1 [Fe+2][H2S] [H+] = square root of {(10 -2.28)(5 10-8)(2.69 10-2)} [H+] = 2.657 10 -6 M/l pH = negative log of the [H+], and the neg log of 2.657 10 -6 = 5.6, so pH = 5.6 Your pH meter is working properly! Chucka( Speading the news around! Psst- A Mountain. ( of trash - LOL; it rhymnes this time!)