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To: dvdw© who wrote (3152)2/8/2010 9:02:15 AM
From: dvdw©Respond to of 3821
 
Troshins sorption theory expanded; In harmony with the ideas first introduced by Martin Fischer (and partially also by Moore and Roaf), Troshin believed that solutes inside the cells in general fall into two categories: adsorbed (or otherwise bound) and dissolved in cell water. He then introduced a two-term equation (Equation Al in Appendix 1), containing a linear term representing solute dissolved in cell water following Henry's Law (or more correctly, in my opinion, the Berthelot-Nernst Distribution Law of which Henry's Law is a special case for solubility of gases in solvents13 pp 696-697), and a "hyperbolic adsorbed" fraction following Langmuir's adsorption isotherm.117 Troshin also showed how the equilibrium distribution of a variety of solutes in living cells as well as coacervate models can be described by the two-term equation. I have repeatedly suggested that this two-term equation be named "Troshin equation" in honor of the author, who died of cancer in 1982.173 p 20; 174 p 285

cacervate models from wiki
en.wikipedia.org