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Strategies & Market Trends : 2026 TeoTwawKi ... 2032 Darkest Interregnum -- Ignore unavailable to you. Want to Upgrade?


To: TobagoJack who wrote (153760)2/29/2020 4:33:40 PM
From: Haim R. Branisteanu  Read Replies (1) | Respond to of 217466
 
Ma see no platinum or iridium or ruthenium

but nickel and rust iron or sulfur or coper


Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide.

Efficient generation of hydrogen from water-splitting is an underpinning chemistry to realize the hydrogen economy. Low cost, transition metals such as nickel and iron-based oxides/hydroxides have been regarded as promising catalysts for the oxygen evolution reaction in alkaline media with overpotentials as low as ~200?mV to achieve 10?mA?cm-2, however, they are generally unsuitable for the hydrogen evolution reaction. Herein, we show a Janus nanoparticle catalyst with a nickel–iron oxide interface and multi-site functionality for a highly efficient hydrogen evolution reaction with a comparable performance to the benchmark platinum on carbon catalyst. Density functional theory calculations reveal that the hydrogen evolution reaction catalytic activity of the nanoparticle is induced by the strong electronic coupling effect between the iron oxide and the nickel at the interface. Remarkably, the catalyst also exhibits extraordinary oxygen evolution reaction activity, enabling an active and stable bi-functional catalyst for whole cell water-splitting with, to the best of our knowledge, the highest energy efficiency (83.7%) reported to date.

Reviewing recent developments in the electrolysis of saline water. Solar-powered technology, such as photovoltaics (PVs) could address some of the environmental challenges of our times, enabling the sustainable production of electrical energy in many geographical areas, including arid or desert regions. Many arid regions are located near an ocean or sea, yet they are typically affected by a scarcity of clean and freshwater. A scarcity of highly purified water, which is required to power most existing electrolyzers, makes storing intermittent solar electricity particularly problematic. Electrolyzers are technological tools that can separate water, typically purified water, into hydrogen and oxygen, through the use of an anode and a cathode. The National University of Ireland the University of Liverpool, Technical University Berlin has conducted a review of recent advancements in materials and catalysts that could enable electrolysis with low-grade or saline water. The first potential opportunity regarding the value of saline water electrolysis, with hydrogen from Australia being shipped to Japan. Hydrogen can be generated from solar electricity in desert areas. A solution can be also found with specific SMR's

The electrolysis of low-grade and saline surface water powered by renewable energy sources such as solar, marine, geothermal and wind, generation of storable hydrogen fuel through water electrolysis provides a promising path towards energy sustainability. However, state-of-the-art electrolysis requires support from associated processes such as desalination of water sources, further purification of desalinated water, and transportation of water, which often contribute to the financial and energy costs. One strategy to avoid these operations is to develop electrolyzers that are capable of operating with impure water feeds directly. Here we review recent developments in electrode materials/catalysts for water electrolysis using low-grade and saline water, a significantly more abundant resource worldwide compared to potable water. We address the associated challenges in the design of electrolyzers and discuss future potential approaches that may yield highly active and selective materials for water electrolysis in the presence of common impurities such as metal ions, chloride, and bio-organisms. Similar results can be achieved with specific SMR's using the sulfur hydrogen & oxygen separation cycle and generate electricity

Sydney, Griffith University & Swinburne University of Technology showed that capturing hydrogen by splitting it from oxygen in water can be achieved by using low-cost metals like iron and nickel as catalysts, which speed up this chemical reaction while requiring less energy. Prof Chuan Zhao says that on their own, iron and nickel are not good catalysts for hydrogen generation, but where they join at the nano-scale is "where the magic happens."

"The nano-scale interface fundamentally changes the property of these materials," he says. "Our results show the nickel-iron catalyst can be as active as the platinum one for hydrogen generation.
"An additional benefit is that our nickel-iron electrode can catalyze both the hydrogen and oxygen generation, so not only could we slash the production costs by using Earth-abundant elements, but also the costs of manufacturing one catalyst instead of two."
A quick glance at today's metal prices shows just why this could be the game-changer needed to speed the transition towards the so-called hydrogen economy. Iron and nickel are priced at $0.13 and $19.65 a kilogram. By contrast, ruthenium, platinum, and iridium are priced at $11.77, $42.13 and $69.58 per gram


Electrolyzer in every district - The possibilities for this new catalyst are manifold. Both in the form of the fuel cell and the reverse reaction in an electrolyzer. For example, fuel cells are used in hydrogen-powered cars while some hospitals already have emergency generators with hydrogen-powered fuel cells. Transporting hydrogen is much cheaper than transporting electricity Hensen's dream goes further. He says, "I hope that we will soon be able to install an electrolyzer in every neighborhood. This refrigerator-sized device stores all the energy from the solar panels on the roofs in the neighborhood during the daytime as hydrogen. The underground gas pipelines will transport hydrogen. The fuel cell will be latter converting the stored hydrogen back into electricity. But for this to happen, the electrolyzer still needs to undergo considerable development. Together with other TU/e researchers and industrial partners from the Brabant region, Hensen is therefore involved in the start-up of the energy institute of TU Eindhoven. The aim is to scale up the current commercial electrolyzers to a refrigerator-size electrolyzer of about 10 megawatts.