To: Raymond Duray who wrote (57471 ) 12/22/2004 10:03:43 PM From: Hugh A Read Replies (2) | Respond to of 74559 Ray - You're right, sort of. At first pass it would seem that increasing pCO2 in the atmosphere and thereby increasing CO2 content in the ocean would be devastating on coral reefs due to formation of carbonic acid and dissolution of coraline carbonate minerals. Today the precipitation rate of calcite (calcium carbonate produced by reef building corals etc.) exceeds its dissolution rate in world oceans down to about 3.5-5 km, the so-called "carbonate compensation depth" (CCD). So, unless we get a massive shallowing in the CCD it is unrealistic to believe that rising pCO2 will cause massive reef dissolution, as is implied in the article I posted. On top of this, the greatest epoch of carbonate sedimentation was the Paleozoic when atmospheric CO2 contents were 8-10 times as high as they are now. Some work I did in the '90s and published in Geochimica et Cosmochimica Acta is relevant here. CO2 acts as an acid as long as the system is unbuffered - this is the reason that some have suggested adding pulverized limestone to the CO2 sequestration stream. However, as we showed, more effective pH buffers are clay minerals, which are abundant in the deep ocean. So although in the simple H2O-CO2 system one might expect massive acidification of the oceans, when one looks at all available sources and sinks for CO2 and H+, the clays are more effective pH buffers (they contain H, no?) and counteract the effects of increasing pCO2. It never ceases to amaze me how reasonably intelligent people of a leftward inclination can look at something and see only the negative implications. Us of the silent majority are slower to anger, but when roused can change dynasties - or perpetuate them. Long live King George II. HA